Jal Jeevan Mission JJM 2022 23 Setting up/Upgradation/ Operation of laboratories for WQMS Procurement of 1No Gas Chromatograph Mass Spectrometer Mass Spectrometer at SRI

OD208340/2023-2024:1. Application requirement: The offered system must achieve at least 0.5 times of acceptable limits mentioned as follows Parameters (Acceptable limit as per the standard10500;2012 (Maximum)) Parameters concerning toxic substances:- Polychlorinated biphenyles (0.0005 mg/l) Poly nuclear aromatic hydrocarbons (as PAH) (0.0001 mg/l) Trihalo methanes:- a. Bromoform (0.1 mg/l) b. Dibromochloromethane (0.1 mg/l) c. Bromo dichloromethane (0.06 mg/l) d. Chloroform (0.2 mg/l) Pesticide residues:- i. Alachlor (20 µg/l) ii. Atrazine (2 µg/l) iii. Aldrin/ Dieldrin (0.03 µg/l) iv. Alpha HCH (0.01 µg/l ) v. Beta HCH (0.04 µg/l) vi. Butachlor (125 µg/l) vii. Chlorpyriphos (30 µg/l) viii. Delta HCH (0.04 µg/l ) ix. DDT (o, p and p, p – Isomers of DDT ,DDE and DDD) (1 µg/l) x. Endosulfan (alpha, beta, and sulphate) (0.4 µg/l) xi. Ethion (3 µg/l) xii. Gamma — HCH (Lindane) (2 µg/l) xiv. Malathion (190 µg/l) xv. Methyl parathion (0.3 µg/l ) xvi. Monocrotophos (1 µg/l) xvii. Phorate (2 µg/l) 2. Gas Chromatograph- Interface 3. The GC must have all features to provide easy accessibility to the GC and immediate interactions with it, such as carrier gas velocity determination, column evaluation etc. System must have the facility to replace the column without breaking the vacuum. 4. Retention Time Repeatability less than 0.01 min 5. Peak area repeatability <1%RSD 6. Oven:- (a) The column oven should have an operating range from ambient+4°C to 400°C or better (b) Fast heat-up time-120 °C/min or more (c) Fast cool-down time 450 °C to 50 °C within 4 minutes or better (d) The oven temperature stability is within 0.01 °C/ every °C of actual temperature (e) The Operating temperature Range should be 4 °C above ambient to ≥400 °C (f) Oven Ramps/Plateaus Cool down:- • It should have number of ramps/plateaus: 20/21 or better 7. Injector –SSL (2 numbers) and auto sampler (a) Maximum temperature: 400 °C (b) Split ratio: Up to 9000:1 or better (c) Pressure range: 0–1000 kPa (0–145 psi) or better (d) Auto sampler should have 150 vial capacity or more 8. Purge and trap concentrator including software for operation and control (a) Purge and trap concentrator for standard methods such as USEPA 502.1, 502.2, 524.2, 524.3, 524.4, 503.1, 601, 602, 603, 624, 8010, 8015, 8020, 8021, 8030, 8240, 8260; fully compatible with the GC-MS system and GC column provided for VOC application, with all required software and accessories for seamless operation and control for the intended applications. (b) Cycle Time: Less than 15 minutes; Trap Furnace: Ambient to 350°C or better, Trap Cooling: Cools from 250° to 40°C in 90 seconds or better; Sample Heater: heater capable of up to 90°C or better (c) Valving: 24VDC motor-actuated 6 port valve. Temperature controlled up to 250°C (d) Sample Glassware: 5mL frit sparger and 5mL needle sparger, One extra 25mL frit sparger and 25 mL needle sparger, and 25mL disposable test tubes. (e) Electronic Mass Flow Controller: System is capable of controlling flow rates from 5mL/min to 500mL/min. Each mode is independently controlled, via software interface (f) Electronic Pressure Monitor: Automatic leak check and over-pressure sensing capability. (g) Operating Conditions: System is capable of operating in a temperature range of 10 - 30°C and a humidity range of 10 - 90%; Corrosion Resistance: The front cover is corrosion resistant to waters with a pH range of 1 -10 Triple Quadrupole Mass Spectrometer 9. Mode (MS):-•It should have Full scan, SIM, timed-SIM, combined full scan/SIM, combined full scan/timed-SIM modes 10. Modes (MS/MS):-•It should have MRM, timed-MRM, combined MRM/full scan, combined timed MRM/full scan, product ion scan 11. Software Features:- (i) It should have Automated MRM Development (ii) It should have Automated acquisition window adjustment based on retention time (iii) It should have Compound based acquisition method setup 12. Ion Source:- (a.) It should have EI source, with dual filaments, temperature up to 350 °C (b.) The system should have improved ion guide (pre filter) to reduce excited neutral background without requiring signal thresholding, background subtraction Or smoothing. Or it should have similar technology such as heated quadrupole/off-axis detector to reduce background noise. 13. Detector (a.) A high sensitivity, high throughput detector with zero dead time, low noise and high accuracy at low level detections. (b)The detection system should have linear range >106 14. Mass Range (a) The mass range should be 10 to 1050 a.m.u. or better. (b) The Triple Stage quadrapole is of inert solid material and should be maintenance free (c) Mass resolution – 0.4 to 3 amu 15. Scan Speed:- (a) The MS should have scan speed > 18000a.m.u/second or better (b) It should have an ability to acquire more than 80 scans/sec in full scan 16. Pumping Systems:- It should have a High capacity (>250 L/s He) turbo molecular pump (TMP) or better 17. Electron Energy:- •It should have an adjustable electron energy from 10 eV to 150 eV or better 18. Emission Current, dual filaments •It should have emission current of 250 μA or better 19. Transfer Line Temperature •The Maximum Temperature should be ≥ 350 °C 20. Performance Specifications using octafluoronaphthalene (OFN) (a) IDL should be less than or equal to 0.5 fg. Vendor need to demonstrate IDL at the time of installation, so reference specs are not acceptable. (b) Full scan and SIM sensitivity must be adequate for the application requirement mentioned. This should be demonstrated. 21. Software Features:- (a) It should have Automated MRM Development (b) It should have Automated acquisition window adjustment based on retention time (c) It should have Compound based MRM Library (d) It should have a software for controlling and acquiring all the GC,MS auto sampler (e) Report Writer Facility should be available according to international Protocols (f) Latest NIIST Library should be provided (g) Chromatography data system for control, acquisition, processing, & Reporting software. (h) Complete system control with user friendly help & system diagnostic. Built in system suitability as per USP/BP etc. (i) 64 – Bit Software design for Windows 7 or above (j) Flexible Reporting as users desires for complete chromatography information Reporting 22. Must perform IQ/OQ/PQ of the system on installation to the satisfaction of customer 23. Accessories:- (i.) Suitable Autosampler syringe - 5 Nos. (ii.) Autosampler vials with cap and septa – 200 Nos. (iii.) Septa for Injector – 50 Nos. (iv.) Column for VOC analysis – 2 Nos. (v.) DB- 5 or equivalent MS column 30m X 0.25 mm X 0.25 – 2 Nos. (vi.) Suitable Syringe for purge and trap concentrator-5 Nos, Filament: 2 Nos extra, Detector: 1 extra (vii.) All relevant accessories/ consumables 24. Local accessories (a) All required gas: 2 cylinders each with suitable regulator (b) UPS:- 10 Kva UPS with 1 hour back up. (c) Computer System:- Latest branded PC compatible with GC with 19’’ LED monitor with Monochrome laser Printer. (d) Suitable table needed to place the equipment and accessories should be provided. (e) 2 nos of AC should be provided in the equipment room. 25. Warranty : 5 years service and replaceable warranty for components. 26. Training: 3 training of 5 days each to the user for the mentioned applications must be provided. This training include hands on and in depth training on the operation and the maintenance of the system as well a specific s application training by application specialist. Note 1. All specification claims of the equipment offered should be substantiated with original brochures 2. The list of existing users of the equipment quoted by the firm should be provided with contact address/phone no./ e mail id etc. 3. Provide sufficient training to the user scientists